Talk:Technetium
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Refs
- R. C. L. Mooney (1948). "Crystal structure of element 43". Acta Cryst. 1 (4): 161–162. doi:10.1107/S0365110X48000466.
- Schwochau K. (1948). "The Present Status of Technetium Chemistry". Radichimica Acta. 21 (1–3): 139–152.
- Berlyn, Graeme P.; Dhillon, Sukhraj S.; Koslow, Evan E. (1980). "Technetium: A toxic waste product of the nuclear fuel cycle: Effects on soybean growth and development". Environmental Management. 4 (2): 149. doi:10.1007/BF01866511.
Inaccuracy in article
The article states that Technetium is found in the Periodic Table "between" Molybdenum and Rhenium. Although that is technically true, the article later states that Technetium is "adjacent" to these two elements. That is not accurate. Technetium is immediately "adjacent" to Molybdenum and Ruthenium in the Periodic Table. Rhenium is to the right of Ruthenium. 96.224.252.16 (talk) 19:52, 15 December 2023 (UTC)
- @96.224.252.16 Sorry for the error. l carelessly confused Molybdenum with Manganese, and Rhodium with Rhenium. Please disregard my foolish mistake. 96.224.252.16 (talk) 20:01, 15 December 2023 (UTC)
The Noddacks
The references to "the Noddacks" in the "Irreproducible Results" paragraph makes sense only to those who know that Walter Noddack married Ida Tacke in the next year (1926); some clarification might be useful here. — Preceding unsigned comment added by 24.170.225.138 (talk) 01:37, 21 August 2025 (UTC)
First isotopes known
I found disputes in which isotope(s) of technetium were discovered first. Is it 95mTc and 97mTc[1], or 99Tc[2]? Either way, 97Tc and 99Tc in the article isotopes of technetium, and 95mTc and 97Tc in the article technetium are incorrect. Nucleus hydro elemon (talk) 08:00, 15 April 2024 (UTC)
The latter reference, given its purpose, should normally be considered the better source for isotope discoveries. But it this case it is complicated, and probably both are right. I wouldn't make a final decision before looking at the original papers from the 1930s, which are paywalled. But here's what seems to be the truth: the first samples of Tc worked with had been made by irradiation of natural molybdenum by protons or deuterons, and were no doubt a mixture of isotopes. Identification as a new element was made by its chemical properties, so the mixture did not matter. It is likely that the first half-lives to be measured were those of 95m and 97m given their value, but the first definite identification of any activity with a mass number was 99m, whose decay by IT allowed the long-lived ground state 99 to be inferred (Thoennessen's compilations do not distinguish isomers). I may change those for now until someone is able to look at those papers and decide the most appropriate wording. 2601:441:8500:B870:DC98:AD98:BDF9:4D9B (talk) 03:51, 16 June 2025 (UTC)
References
- ^ Johnstone, Erik V.; Mayordomo, Natalia; Mausolf, Edward J. (2022-10-20). "Discovery, nuclear properties, synthesis and applications of technetium-101". Communications Chemistry. 5 (1). doi:10.1038/s42004-022-00746-9. ISSN 2399-3669. PMC 9814870. PMID 36697915.
- ^ Nystrom, A.; Thoennessen, M. (2012). "Discovery of yttrium, zirconium, niobium, technetium, and ruthenium isotopes". Atomic Data and Nuclear Data Tables. 98 (2): 95–119. doi:10.1016/j.adt.2011.12.002.