Zirconium acetate usually refers to the chemical formula Zr6O4(OH)4(O2CCH3)12. It forms by the reaction of zirconyl chloride and acetate. Claims of Zr(O2CCH3)4[1] have been superseded by experiments using X-ray crystallography.[2]
The species Zr6O4(OH)4(O2CCH3)12 is a common precursor to metal-organic frameworks (MOFs).[3]
References
- ^ Pavlov, V. L.; Lysenko, Yu. A.; Kalinichenko, A. A. Synthesis and properties of zirconium tetraacetate.(in Russian) Zhurnal Neorganicheskoi Khimii, 1972. 17(12). ISSN 0044-457X
- ^ Hennig, Christoph; Weiss, Stephan; Kraus, Werner; Kretzschmar, Jerome; Scheinost, Andreas C. (2017). "Solution Species and Crystal Structure of Zr(IV) Acetate". Inorganic Chemistry. 56 (5): 2473–2480. doi:10.1021/acs.inorgchem.6b01624. PMID 28199091.
- ^ Cavka, Jasmina Hafizovic; Jakobsen, Søren; Olsbye, Unni; Guillou, Nathalie; Lamberti, Carlo; Bordiga, Silvia; Lillerud, Karl Petter (2008). "A New Zirconium Inorganic Building Brick Forming Metal Organic Frameworks with Exceptional Stability". Journal of the American Chemical Society. 130 (42): 13850–13851. Bibcode:2008JAChS.13013850C. doi:10.1021/ja8057953. PMID 18817383.
