Biofuel: Difference between revisions
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! [[Orders of magnitude (specific energy density)|Specific Energy Density]] <br/> ([[Joule|MJ]]/[[kilogram|kg]]) |
! [[Orders of magnitude (specific energy density)|Specific Energy Density]] <br/> ([[Joule|MJ]]/[[kilogram|kg]]) |
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! Volumetric Energy Density <br/> ([[Joule|MJ]]/[[litre|l]]) |
! Volumetric Energy Density <br/> ([[Joule|MJ]]/[[litre|l]]) |
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! [[Carbon dioxide|CO<sub>2</sub>]] gas made from Fuel Used <br/> ([[kilogram|kg]]/[[kilogram|kg]]) |
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! colspan=" |
! colspan="4" | Solid Fuels |
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|[[Wood fuel]] |
|[[Wood fuel]] |
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|align ="right"| 16 – 21 |
|align ="right"| 16 – 21 |
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|align ="right"| |
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|- |
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|Dried plants |
|Dried plants |
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|align ="right"| 10 – 16 |
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|- |
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|Animal waste |
|Animal waste |
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|align ="right"| |
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|- |
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|[[Chaff]] |
|[[Chaff]] |
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|[[Bagasse]] |
|[[Bagasse]] |
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|align ="right"| 9.6 |
|align ="right"| 9.6 |
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|align ="right"| |
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|- |
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! colspan=" |
! colspan="4" align ="center" | Liquid Fuels |
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|- |
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|[[Methanol]] |
|[[Methanol]] |
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|align ="right"| 19.9 – 22.7 |
|align ="right"| 19.9 – 22.7 |
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|align ="right"| 15.9 |
|align ="right"| 15.9 |
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|align ="right"| 1.37 |
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|- |
|- |
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|[[Ethanol]] |
|[[Ethanol]] |
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|align ="right"| 23.4 – 26.8 |
|align ="right"| 23.4 – 26.8 |
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|align ="right"| 23.4 |
|align ="right"| 23.4 |
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|align ="right"| 1.91 |
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|- |
|- |
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|[[Butanol]] |
|[[Butanol]] |
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|align ="right"| 36.0 |
|align ="right"| 36.0 |
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|align ="right"| 29.2 |
|align ="right"| 29.2 |
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|align ="right"| |
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|Vegetable oil |
|Vegetable oil |
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|align ="right"| 37.8 |
|align ="right"| 37.8 |
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|align ="right"| 33.3 – 35.7 |
|align ="right"| 33.3 – 35.7 |
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! colspan=" |
! colspan="4" align ="center" | Gaseous Fuels |
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|[[Methane]] |
|[[Methane]] |
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|align ="right"| 55 – 55.7 |
|align ="right"| 55 – 55.7 |
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|align ="center"| Compression Dependent |
|align ="center"| Compression Dependent |
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|align ="right"| ~2.7 ([[Carbon dioxide|CO<sub>2</sub>]] exerts 1/23 [[greenhouse gas|greenhouse]] effect of [[Methane]] leek) |
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|[[Hydrogen]] |
|[[Hydrogen]] |
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|align ="right"| 120 – 142 |
|align ="right"| 120 – 142 |
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|align ="center"| Compression Dependent |
|align ="center"| Compression Dependent |
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|align ="right"| 0.0 |
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|- |
|- |
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! colspan=" |
! colspan="4" align ="center" | Fossil Fuels (comparison) |
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|- |
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|[[Coal]] |
|[[Coal]] |
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|align ="right"| 29.3 – 33.5 |
|align ="right"| 29.3 – 33.5 |
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|align ="right"| |
|align ="right"| |
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|align ="right"| ~3.0 (not counting [[Carbon monoxide|Monoxides]], [[Sulfide|Sulfides]] & [[Particulate|Particulates]]) |
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|[[Gasoline]] |
|[[Gasoline]] |
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|align ="right"| 45 – 48.3 |
|align ="right"| 45 – 48.3 |
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|align ="right"| 32 – 34.8 |
|align ="right"| 32 – 34.8 |
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|align ="right"| ~2.36 |
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|[[Diesel]] |
|[[Diesel]] |
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|align ="right"| 48.1 |
|align ="right"| 48.1 |
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|align ="right"| 40.3 |
|align ="right"| 40.3 |
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|align ="right"| ~2.5 (not counting [[Carbon monoxide|Monoxides]], [[Sulfide|Sulfides]] & [[Particulate|Particulates]]) |
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|[[Natural Gas]] |
|[[Natural Gas]] |
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|align ="right"| 38 – 50 |
|align ="right"| 38 – 50 |
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|align ="center"| Compression Dependent |
|align ="center"| Compression Dependent |
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|align ="right"| ~1.65 |
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|- |
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|[[Uranium-235]] |
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|align ="right"| (77 – 90) * 10^6 |
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|align ="center"| Purity Dependent |
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|align ="center"| [Higher with lower Ore conc.(Mining,Refining,Moving)] |
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|- |
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|[[Nuclear fusion]] ([[Deuterium|D]]-[[Tritium|T]]) |
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|align ="right"| 300 * 10^6 |
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|align ="center"| Compression Dependent |
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|align ="center"| 0.0 [Sea-Bed Hydrogen-Isotope Mining-Method Dependent] |
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|- |
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! colspan="4" align ="center" | Fuel Cell Energy Storage (comparison) |
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|[[Direct-methanol fuel cell|Direct-Methanol]] |
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|align ="right"| 4.5466 |
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|align ="right"| 3.6 [http://uk.computers.toshiba-europe.com/cgi-bin/ToshibaCSG/news_article.jsp?service=UK&ID=0000005758] |
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|align ="right"| ~1.4 |
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|- |
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|[[Proton exchange membrane fuel cell|Proton-Exchange (R&D)]] |
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|align ="right"| upto 5.68 |
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|align ="right"| upto 4.5 |
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|align ="right"| 0.0 (IFF Fuel is recycled) |
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|[[Alkaline fuel cell|Sodium Hydride (R&D)]] |
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|align ="right"| upto 12.93 |
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|align ="right"| upto 10.24 |
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|align ="right"| 0.0 (Bladder for Sodium Oxide Recycling) |
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|- |
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! colspan="4" align ="center" | Battery Energy Storage (comparison) |
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|[[Lead-acid battery|Lead-acid]] |
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|align ="right"| 0.108 |
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|align ="right"| |
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|align ="right"| 0.0 |
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|[[Nickel-cadmium battery|NiCad]] |
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|align ="right"| ~0.2 |
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|align ="right"| ~0.2 |
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|align ="right"| 0.0 |
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|[[Nickel metal hydride battery|NiMH]] |
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|align ="right"| 0.22 |
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|align ="right"| 0.36 |
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|align ="right"| 0.0 |
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|- |
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|[[Zinc-air battery]] |
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|align ="right"| 0.4 - 0.72 |
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|align ="right"| |
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|align ="right"| 0.0 |
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|[[Lithium ion battery|Lithium-Ion]] |
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|align ="right"| 0.54 - 0.72 |
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|align ="right"| 0.9 - 1.9 |
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|align ="right"| 0.0 |
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|[[Lithium ion polymer battery|Lithium-Ion-Polymer]] |
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|align ="right"| 0.65 - 0.87 |
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|align ="right"| 1.08 - 2.28 |
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|align ="right"| 0.0 |
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Revision as of 11:28, 23 April 2006
- This article is about the general topic of biofuel. For articles on specific fuels used in vehicles, see Ethanol fuel and Biodiesel.
Biofuel is any fuel that derives from biomass — recently living organisms or their metabolic byproducts, such as manure from cows. It is a renewable energy source, unlike other natural resources such as petroleum, coal and nuclear fuels.
Agricultural products specifically grown for use as biofuels include corn and soybeans, primarily in the United States, as well as flaxseed and rapeseed, primarily in Europe. Waste from industry, agriculture, forestry, and households can also be used to produce bioenergy; examples include straw, lumber, manure, sewage, garbage and food leftovers. Most biofuel is burned to release its stored chemical energy. The largest advantage of biofuel in comparison to most other fueltypes is that the energy within the biomass can be stored for an indefinite time-period and without any danger.
Biomass can be used both for central- and decentralized production of electricity and heat. As of 2005, bioenergy covers approximately 15% of the world's energy consumption. Most bioenergy is consumed in developing countries and is used for direct heating, as opposed to electricity production. However, Sweden and Finland supply 17% and 19% [1] respectively, of their energy needs with bioenergy, a high figure for industrialized countries.
The production of biofuels to replace oil and natural gas is in active development, focusing on the use of cheap organic matter (usually cellulose, agricultural and sewage waste) in the efficient production of liquid and gas biofuels which yield high net energy gain. The carbon in biofuels was recently extracted from atmospheric carbon dioxide by growing plants, so burning it does not result in a net increase of carbon dioxide in the Earth's atmosphere. As a result, biofuels are seen by many as a way to reduce the amount of carbon dioxide released into the atmosphere by using them to replace non-renewable sources of energy. Noticeable is the fact that the quality of timber or grassy biomass does not have a direct impact on its value as an energy-source.
Dried compressed peat is also sometimes considered a biofuel. However it does not meet the criteria of being a renewable form of energy, or of the carbon being recently absorbed from atmospheric carbon dioxide by growing plants. Though more recent than petroleum or coal, on the time scale of human industrialisation it is a fossil fuel and burning it does contribute to atmospheric CO2.
Liquid
There are also a number of liquid forms of biomass that can be used as a fuel:
- Bioalcohols — see ethanol fuel.
- Ethanol fuel produced from sugar cane is being used as automotive fuel in Brazil. Ethanol produced from corn is being used as a gasoline additive (oxygenator) in the United States. Cellulostic ethanol is being manufactured from straw (an agricultural waste product) by Iogen Corporation of Ontario, Canada.
- Methanol, which is currently produced from natural gas, can also be produced from biomass — although this is not economically viable at present. The methanol economy is an interesting alternative to the hydrogen economy.
- Butanol is formed by A.B.E. fermentation (Acetone, Butanol Ethanol) and experimental modifications of the ABE process show potentially high net energy gains with butanol being the only liquid product. Butanol can be burned "straight" in existing gasoline engines (without modification to the engine or car), produces more energy and is less corrosive and less water soluble than ethanol, and can be distributed via existing infrastructures.
- Biologically produced oils (bio-oils) can be used in diesel engines :
- Straight vegetable oil (SVO).
- Waste vegetable oil (WVO).
- Biodiesel obtained from transesterification of animal fats and vegetable oil, directly usable in petroleum diesel engines.
- Oils and gases can be produced from various wastes:
Gaseous
- Bio-methane produced by the natural decay of garbage or agricultural manure can be collected for use as fuel.
- It is also possible to estimate the number of animals needed for desirable size of biogas driven engine with Biogas Calculator
- Wood gas can be extracted from wood and used in petrol engines.
- Hydrogen can be produced in water electrolysis or, less ecologically, by cracking any hydrocarbon fuel in a reformer, some fermentation processes also produce hydrogen, such as A.B.E. fermentation.
- Gasification, that produces carbon monoxide.
Other
One company, GreenFuel Technologies Corporation, has developed a patented bioreactor system that utilizes nontoxic photosynthetic algae to take in smokestacks flue gases and produce biofuels such as biodiesel, bio-gas (similar to natural gas), and a dry fuel comparable to coal [2].
Energy content of Biofuel
| fuel type | Specific Energy Density (MJ/kg) |
Volumetric Energy Density (MJ/l) |
CO2 gas made from Fuel Used (kg/kg) |
|---|---|---|---|
| Solid Fuels | |||
| Wood fuel | 16 – 21 | ||
| Dried plants | 10 – 16 | ||
| Animal waste | |||
| Chaff | |||
| Bagasse | 9.6 | ||
| Liquid Fuels | |||
| Methanol | 19.9 – 22.7 | 15.9 | 1.37 |
| Ethanol | 23.4 – 26.8 | 23.4 | 1.91 |
| Butanol | 36.0 | 29.2 | |
| Vegetable oil | |||
| Biodiesel | 37.8 | 33.3 – 35.7 | |
| Gaseous Fuels | |||
| Methane | 55 – 55.7 | Compression Dependent | ~2.7 (CO2 exerts 1/23 greenhouse effect of Methane leek) |
| Hydrogen | 120 – 142 | Compression Dependent | 0.0 |
| Fossil Fuels (comparison) | |||
| Coal | 29.3 – 33.5 | ~3.0 (not counting Monoxides, Sulfides & Particulates) | |
| Gasoline | 45 – 48.3 | 32 – 34.8 | ~2.36 |
| Diesel | 48.1 | 40.3 | ~2.5 (not counting Monoxides, Sulfides & Particulates) |
| Natural Gas | 38 – 50 | Compression Dependent | ~1.65 |
| Uranium-235 | (77 – 90) * 10^6 | Purity Dependent | [Higher with lower Ore conc.(Mining,Refining,Moving)] |
| Nuclear fusion (D-T) | 300 * 10^6 | Compression Dependent | 0.0 [Sea-Bed Hydrogen-Isotope Mining-Method Dependent] |
| Fuel Cell Energy Storage (comparison) | |||
| Direct-Methanol | 4.5466 | 3.6 [3] | ~1.4 |
| Proton-Exchange (R&D) | upto 5.68 | upto 4.5 | 0.0 (IFF Fuel is recycled) |
| Sodium Hydride (R&D) | upto 12.93 | upto 10.24 | 0.0 (Bladder for Sodium Oxide Recycling) |
| Battery Energy Storage (comparison) | |||
| Lead-acid | 0.108 | 0.0 | |
| NiCad | ~0.2 | ~0.2 | 0.0 |
| NiMH | 0.22 | 0.36 | 0.0 |
| Zinc-air battery | 0.4 - 0.72 | 0.0 | |
| Lithium-Ion | 0.54 - 0.72 | 0.9 - 1.9 | 0.0 |
| Lithium-Ion-Polymer | 0.65 - 0.87 | 1.08 - 2.28 | 0.0 |
Examples
One widespread use of biofuels is in home cooking and heating. Typical fuels for this are wood, charcoal or dried dung. The biofuel may be burned on an open fireplace or in a special stove. The efficiency of this process may vary widely, from 10% for a well made fire (even less if the fire is not made carefully) up to 40% for a custom designed charcoal stove1. Inefficient use of fuel may be a minor cause of deforestation (though this is negligible compared to deliberate destruction to clear land for agricultural use) but more importantly it means that more work has to be put into gathering fuel, thus the quality of cooking stoves has a direct influence on the viability of biofuels.
"American homeowners are turning to burning corn in special stoves to reduce their energy bills. Sales of corn-burning stoves have tripled this year [...] Corn-generated heat costs less than a fifth of the current rate for propane and about a third of electrical heat" [4].
- Use on farms
In Germany small scale use of biofuel is still a domain of agricultural farms. It is an official aim of the German government to use the entire potential of 200,000 farms for the production of biofuel and bioenergy. (Source: VDI-Bericht "Bioenergie - Energieträger der Zukunft".
- Smallscale use
Different combustion-engines are being produced for very low prices lately [[5]]. They allow the private house-owner to utilize low amounts of "weak" compression of methan to generate electrical and thermal power (almost) sufficient for a well insulated residential home.
Problems and solutions
Unfortunately, much cooking with biofuels is done indoors, without efficient ventilation, and using fuels such as dung causes airborne pollution. This can be a serious health hazard; 1.5 million deaths were attributed to this cause by the World Health Organisation as of 2000 2. There are various responses to this, such as improved stoves, including those with inbuilt flues and switching to alternative fuel sources. Most of these responses have difficulties. One is that flues are expensive and easily damaged. Another is that alternative fuels tend to be more expensive, but the people who rely on biofuels often do so precisely because they cannot afford alternatives. 3 Organisations such as Intermediate Technology Development Group work to make improved facilities for biofuel use and better alternatives accessible to those who cannot currently get them. This work is done through improving ventilation, switching to different uses of biomass such as the creation of biogas from solid biomatter, or switching to other alternatives such as micro-hydro power.
International efforts
On the other hand, recognizing the importance of bioenergy and its implementation, there are international organizations such as IEA Bioenergy, established in 1978 by the International Energy Agency (IEA), with the aim of improving cooperation and information exchange between countries that have national programs in bioenergy research, development and deployment.
See also
- Alcohol as a fuel
- Biomass to liquid
- Biodiesel
- Elephant grass
- Switch grass
- Environmentalism
- Pyrolysis
- Thermal depolymerization
- Waste vegetable oil
References
- Biomass Technical Brief, Simon Ekless, Intermediate Technology Development Group, retrieved 1 January 2005 from http://www.itdg.org/docs/technical_information_service/biomass.pdf.
- Smoke — the killer in the kitchen, Intermediate Technology Development Group, 19 March 2004, retrieved 1 January 2005 from http://www.itdg.org/?id=smoke_report_1
- Reducing exposure to indoor air pollution, Intermediate Technology Development Group, 19 March 2004, retrieved 1 January 2005 from http://www.itdg.org/?id=smoke_report_3