Diphenylsilanediol, Ph2Si(OH)2, is a silanol. The tetrahedral molecule forms hydrogen-bonded columns in the solid state.[4] It can be prepared by hydrolysis of diphenyldichlorosilane Ph2SiCl2. Diphenylsilanediol can act as an anticonvulsant, in a similar way to phenytoin.[4] Although the compound is stable in normal conditions, the presence of basic impurities can accelerate the condensation of the silanol groups.

References

  1. ^ a b "GESTIS-Stoffdatenbank".
  2. ^ T. J. Kistenmacher; M. Rossi; L. K. Frevel (October 1978). "Crystal data for diphenylsilanediol, (C6H3)2Si(OH)2". J. Appl. Crystallogr. 11 (5): 670–671. doi:10.1107/S002188987801420X.
  3. ^ Neal, D. J.; Blaumanis, R. D. (1960). "Crystallographic Data. 187. Diphenylsilanediol". Analytical Chemistry. 32: 139. doi:10.1021/ac60157a047.
  4. ^ a b J. K. Fawcett; N. Camerman; A. Camerman (1977). "Stereochemical basis of anticonvulsant drug action. VI. Crystal and molecular structure of diphenylsilanediol". Can. J. Chem. 55 (20): 3631–3635. doi:10.1139/v77-510.
Allikas: https://en.wikipedia.org/wiki/Diphenylsilanediol
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