Chromium(III) 2-ethylhexanoate, C24H45CrO6, is a coordination complex of chromium and ethylhexanoate. In combination with 2,5-dimethylpyrrole it forms the Phillips selective ethylene trimerisation catalyst[3] (not to be confused with Phillips catalyst), used in the industrial production of linear alpha olefins, particularly 1-hexene or 1-octene.[4]

References

  1. ^ Venderbosch, Bas; Oudsen, Jean-Pierre H.; Wolzak, Lukas A.; Martin, David J. ; Korstanje, Ties J.; Tromp, Moniek. Spectroscopic Investigation of the Activation of a Chromium-Pyrrolyl Ethene Trimerization Catalyst. ACS Catalysis (2019), 9(2), 1197-1210. doi:10.1021/acscatal.8b03414.
  2. ^ a b c NIOSH Pocket Guide to Chemical Hazards. "#0141". National Institute for Occupational Safety and Health (NIOSH).
  3. ^ Naji-Rad, Ebtehal; Gimferrer, Martí; Bahri-Laleh, Naeimeh; Nekoomanesh-Haghighi, Mehdi; Jamjah, Roghieh; Poater, Albert (24 May 2018). "Exploring Basic Components Effect on the Catalytic Efficiency of Chevron-Phillips Catalyst in Ethylene Trimerization". Catalysts. 8 (6): 224. doi:10.3390/catal8060224. hdl:10256/15519.
  4. ^ Agapie, Theodor (April 2011). "Selective ethylene oligomerization: Recent advances in chromium catalysis and mechanistic investigations". Coordination Chemistry Reviews. 255 (7–8): 861–880. doi:10.1016/j.ccr.2010.11.035.
Allikas: http://en.wikipedia.org/wiki/Chromium(III)_2-ethylhexanoate
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