Lutetium(III) acetate is the acetate salt of lutetium with the chemical formula of Lu(CH3COO)3.

Preparation

Lutetium(III) acetate can be prepared through neutralisation, where a lutetium salt reacts with acetic acid to produce lutetium acetate and water:

Lu2O3 + 6 CH3COOH → 2 Lu(CH3COO)3 + 3 H2O
Lu(OH)3 + 3 CH3COOH → Lu(CH3COO)3 + 3 H2O

Lutetium(III) acetate also can be obtained by reacting lutetium oxide with gaseous acetic acid[1] or 50% acetic acid solution.[2]

Properties

Lutetium(III) acetate is a water-soluble salt that forms colorless crystals. It forms crystalline hydrates in the form of Lu(CH3COO)3•nH2O, where n = 1 or 4.[citation needed]

Lutetium(III) acetate reacts with ammonium fluoride to produce lutetium fluoride:

Lu(CH3COO)3 + 3 NH4F → LuF3 + 3 CH3COONH4

The F− formed by the hydrolysis of fluoroborates (such as [BMIM]BF4)[3] can also precipitate with Lu3+.[4]

Reaction with phosphoric acid to produce lutetium phosphate:[5]

Lu(CH3COO)3 + H3PO4 → LuPO4 + 3 CH3COOH

References

  1. ^ Janina Wysocka-Lisek. Study of topochemical preparation of rare earth acetates(in Polish). Biuletyn Lubelskiego Towarzystwa Naukowego, Matematyka-Fizyka-Chemia, 1981. 23 (2): 145-149.
  2. ^ Grählert, Xina; Starke, Graehlert (1992). "Preparation, thermogravimetric study and infrared spectra of rare earth acetates". Preparation, Thermogravimetric Study and Infrared Spectra of Rare Earth Acetates. 34 (2): 219–229.
  3. ^ Note: The original text is "BMIM = 1-butyl-2-methylimidazolium", which is supposed to be 1-butyl-3-methylimidazolium
  4. ^ Becerro, Ana I.; Gonzalez-Mancebo, Daniel; Ocaña, Manuel (January 2015). "Uniform, luminescent Eu:LuF3 nanoparticles". Journal of Nanoparticle Research. 17 (1): 58. Bibcode:2015JNR....17...58B. doi:10.1007/s11051-015-2874-z. hdl:10261/110370. S2CID 73703723.
  5. ^ Becerro, Ana I.; Ocaña, Manuel (2015). "Quick synthesis, functionalization and properties of uniform, luminescent LuPO 4 -based nanoparticles". RSC Advances. 5 (44): 34517–34524. Bibcode:2015RSCAd...534517B. doi:10.1039/C5RA05305F. hdl:11441/73018.
Allikas: Https://en.wikipedia.org/wiki/Lutetium(III)_acetate
No tags for this post.