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English: Jablonski diagram of absorbance, non-radiative decay, and fluorescence.

Electronic transitions are about 1 eV. Vibrational transitions are about 0.1 eV. Rotational transitions (not shown) are about 0.001 eV. Absorption is about 1 femtosecond, relaxation takes about 1 picosecond, fluorescence takes about 1 nanosecond.

S0 and S1 represent different electronic states. The other numbers (here 0–3 are shown) represent vibrational states.
Русский: Диаграмма Яблонского для флуоресценции, поглощения и безизлучательных переходов.
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Source File:Jablonski Diagram of Fluorescence Only.png by Jacobkhed
Author Д.Ильин: vectorization
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7 December 2021

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