Terphenyls are a group of closely related aromatic hydrocarbons. Also known as diphenylbenzenes or triphenyls, they consist of a central benzene ring substituted with two phenyl groups. There are three substitution patterns: ortho-terphenyl, meta-terphenyl, and para-terphenyl. Commercial grade terphenyl is generally a mixture of the three isomers. This mixture is used in the production of polychlorinated terphenyls, which were formerly used as heat storage and transfer agents.[2]
p-Terphenyl derivatives are found in various fungi and bacteria. One example is atromentin, a pigment found in some mushrooms. These natural p-terphenyls are better described as diphenylquinones or diphenylhydroquinones. Some m-terphenyl compounds occur in plants.[8]
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ortho-Terphenyl
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meta-Terphenyl
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para-Terphenyl
See also
- Biphenyl
- Terpyridine
- Terthiophene
- OMRE, experimental organic nuclear reactor that tested terphenyl as reactor coolant
References
- ^ a b Nomenclature of Organic Chemistry : IUPAC Recommendations and Preferred Names 2013 (Blue Book). Cambridge: The Royal Society of Chemistry. 2014. p. 345. doi:10.1039/9781849733069-00130. ISBN 978-0-85404-182-4.
- ^ a b c d p-Terphenyl at chemicalland21.com
- ^ "Organic molecular single crystals". cryos-beta.kharkov.ua.
- ^ a b c p-Terphenyl at Sigma-Aldrich
- ^ NIOSH Pocket Guide to Chemical Hazards. "#0591". National Institute for Occupational Safety and Health (NIOSH).
- ^ NIOSH Pocket Guide to Chemical Hazards. "#0592". National Institute for Occupational Safety and Health (NIOSH).
- ^ NIOSH Pocket Guide to Chemical Hazards. "#0593". National Institute for Occupational Safety and Health (NIOSH).
- ^ Liu, Ji-Kai (2006). "Natural Terphenyls: Developments since 1877". Chemical Reviews. 106 (6): 2209–2223. doi:10.1021/cr050248c. PMID 16771447.
External links
- p-Terphenyl at the Oregon Laser Medical Center
- o-Terphenyl, m-Terphenyl, p-Terphenyl at Centers for Disease Control and Prevention, National Institute for Occupational Safety and Health
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