Leão (Portuguese for lion) may refer to:
- Émerson Leão (born 1949), Brazilian manager and former footballer
- Nara Leão (1942–1989), Brazilian bossa nova and MPB (popular Brazilian music) singer and occasional actress
- Aristides Leão (1914–1993), Brazilian biologist and scientist
- André Leão (born 1985), Portuguese footballer
- Augusto Pinto Duarte Maia (born 1971), Portuguese footballer known as Leão
- Rafael Leão (born 1999), Portuguese footballer
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