Palladium(II) perchlorate is an inorganic chemical compound with the formula Pd(ClO4)2. It is a light-brown solid produced by the reaction of dichlorine hexoxide and palladium(II) chloride followed by heating at 60 °C in a vacuum:[1]

3 PdCl2 + 4 Cl2O6 → 3 Pd(ClO4)2 + 4 Cl2

Aqueous solutions of palladium(II) perchlorate can be produced by the addition of perchloric acid to a solution of palladium(II) nitrate.[2]

Structure

Solid anhydrous palladium(II) perchlorate consists of a pair of bidentate perchlorate ligands attached to the central palladium atom.[1]

References

  1. ^ a b Frédérique Cunin; Frédéric Favier; Jean Louis Pascal (2000). "Anhydrous perchlorato complexes of palladium(II): Pd(ClO4)2, (ClO2)2Pd(ClO4)4, and (NO2)2Pd(ClO4)4. Syntheses and structural analyses". Canadian Journal of Chemistry. 78 (12): 1544–1522. doi:10.1139/v00-149.
  2. ^ A. K. Sundaram; E. B. Sandell (1955). "Chloro Complexes of Palladium(II) in Solution". Journal of the American Chemical Society. 77 (4): 855–857. doi:10.1021/ja01609a008.
Allikas: https://en.wikipedia.org/wiki/Palladium(II)_perchlorate
No tags for this post.