Phospholane is the organophosphorus compound with the formula (CH2)4PH. This colorless liquid is the parent member of a family of five-membered, saturated rings containing phosphorus. Although phospholane itself is only of minor academic interest, the class of C- and P-substituted phospholanes are valued ligands in asymmetric hydrogenation and related areas of homogeneous catalysis.[2] Phospholane is prepared by reduction of 1-chlorophospholane, which in turn is obtained by the reaction of 1-phenylphospholane and phosphorus trichloride.[3]

DuPhos is one of several phospholane ligands.

References

  1. ^ Nomenclature of Organic Chemistry : IUPAC Recommendations and Preferred Names 2013 (Blue Book). Cambridge: The Royal Society of Chemistry. 2014. pp. 392, 599. doi:10.1039/9781849733069. ISBN 978-0-85404-182-4.
  2. ^ Clark, Thomas; Landis, Clark (2004). "Recent developments in chiral phospholane chemistry". Tetrahedron: Asymmetry. 15: 2123–2137. doi:10.1016/j.tetasy.2004.06.025.
  3. ^ K. Sommer (1970). "Zur Spaltung tertiärer Phosphine. II". Zeitschrift für Anorganische und Allgemeine Chemie. 379: 56–62. doi:10.1002/zaac.19703790110.
Allikas: https://en.wikipedia.org/wiki/Phospholane
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